Essays: Scientific, Political, & Speculative (Vol. 1-3). Spencer Herbert

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СКАЧАТЬ it anything still more speculative. For this reason I have decided to set forth separately some views concerning the genesis of the so-called elements during nebular condensation, and concerning the accompanying physical effects. At the same time it has seemed best to detach from the essay some of the more debatable conclusions originally contained in it; so that its general argument may not be needlessly implicated with them. These new portions, together with the old portions which re-appear more or less modified, I here append in a series of notes.

      Note I. For the belief that the so-called elements are compound there are both special reasons and general reasons. Among the special may be named the parallelism between allotropy and isomerism; the numerous lines in the spectrum of each element; and the cyclical law of Newlands and Mendeljeff. Of the more general reasons, which, as distinguished from these chemical or chemico-physical ones, may fitly be called cosmical, the following are the chief.

      The general law of evolution, if it does not actually involve the conclusion that the so-called elements are compounds, yet affords a priori ground for suspecting that they are such. The implication is that, while the matter composing the Solar System has progressed physically from that relatively-homogeneous state which it had as a nebula to that relatively-heterogeneous state presented by Sun, planets, and satellites, it has also progressed chemically, from the relatively-homogeneous state in which it was composed of one or a few types of matter, to that relatively-heterogeneous state in which it is composed of many types of matter very diverse in their properties. This deduction from the law which holds throughout the cosmos as now known to us, would have much weight even were it unsupported by induction; but a survey of chemical phenomena at large discloses several groups of inductive evidences supporting it.

      The first is that since the cooling of the Earth reached an advanced stage, the components of its crust have been ever increasing in heterogeneity. When the so-called elements, originally existing in a dissociated state, united into oxides, acids, and other binary compounds, the total number of different substances was immensely augmented, the new substances were more complex than the old, and their properties were more varied. That is, the assemblage became more heterogeneous in its kinds, in the composition of each kind, and in the range of chemical characters. When, at a later period, there arose salts and other compounds of similar degrees of complexity, there was again an increase of heterogeneity, alike in the aggregate and in its members. And when, still later, matters classed as organic became possible, the multiformity was yet further augmented in kindred ways. If, then, chemical evolution, so far as we can trace it, has been from the homogeneous to the heterogeneous, may we not fairly suppose that it has been so from the beginning? If, from late stages in the Earth's history, we run back, and find the lines of chemical evolution continually converging, until they bring us to bodies which we cannot decompose, may we not suspect that, could we run back these lines still further, we should come to still decreasing heterogeneity in the number and nature of the substances, until we reached something like homogeneity?

      A parallel argument may be derived from consideration of the affinities and stabilities of chemical compounds. Beginning with the complex nitrogenous bodies out of which living things are formed, and which, in the history of the Earth, are the most modern, at the same time that they are the most heterogeneous, we see that the affinities and stabilities of these are extremely small. Their molecules do not enter bodily into union with those of other substances so as to form more complex compounds still, and their components often fail to hold together under ordinary conditions. A stage lower in degree of composition we come to the vast assemblage of oxy-hydro-carbons, numbers of which show many and decided affinities, and are stable at common temperatures. Passing to the inorganic group, we are shown by the salts &c. strong affinities between their components and unions which are, in many cases, not very easily broken. And then when we come to the oxides, acids, and other binary compounds, we see that in many cases the elements of which they are formed, when brought into the presence of one another under favourable conditions, unite with violence; and that many of their unions cannot be dissolved by heat alone. If, then, as we go back from the most modern and most complex substances to the most ancient and simplest substances, we see, on the average, a great increase in affinity and stability, it results that if the same law holds with the simplest substances known to us, the components of these, if they are compound, may be assumed to have united with affinities far more intense than any we have experience of, and to cling together with tenacities far exceeding the tenacities with which chemistry acquaints us. Hence the existence of a class of substances which are undecomposable and therefore seem simple, appears to be an implication; and the corollary is that these were formed during early stages of terrestrial concentration, under conditions of heat and pressure which we cannot now parallel.

      Yet another support for the belief that the so-called elements are compounds, is derived from a comparison of them, considered as an aggregate ascending in their molecular weights, with the aggregate of bodies known to be compound, similarly considered in their ascending molecular weights. Contrast the binary compounds as a class with the quaternary compounds as a class. The molecules constituting oxides (whether alkaline or acid or neutral) chlorides, sulphurets, &c. are relatively small; and, combining with great avidity, form stable compounds. On the other hand, the molecules constituting nitrogenous bodies are relatively vast and are chemically inert; and such combinations as their simpler types enter into, cannot withstand disturbing forces. Now a like difference is seen if we contrast with one another the so-called elements. Those of relatively-low molecular weights—oxygen, hydrogen, potassium, sodium, &c.—show great readiness to unite among themselves; and, indeed, many of them cannot be prevented from uniting under ordinary conditions. Contrariwise, under ordinary conditions the substances of high molecular weights—the "noble metals"—are indifferent to other substances; and such compounds as they do form under conditions specially adjusted, are easily destroyed. Thus as, among the bodies we know to be compound, increasing molecular weight is associated with the appearance of certain characters, and as, among the bodies we class as simple, increasing molecular weight is associated with the appearance of similar characters, the composite nature of the elements is in another way pointed to.

      There has to be added one further class of phenomena, congruous with those above named, which here specially concerns us. Looking generally at chemical unions, we see that the heat evolved usually decreases as the degree of composition, and consequent massiveness, of the molecules, increases. In the first place, we have the fact that during the formation of simple compounds the heat evolved is much greater than that which is evolved during the formation of complex compounds: the elements, when uniting with one another, usually give out much heat; while, when the compounds they form are recompounded, but little heat is given out; and, as shown by the experiments of Prof. Andrews, the heat given out during the union of acids and bases is habitually smaller where the molecular weight of the base is greater. Then, in the second place, we see that among the elements themselves, the unions of those having low molecular weights result in far more heat than do the unions of those having high molecular weights. If we proceed on the supposition that the so-called elements are compounds, and if this law, if not universal, holds of undecomposable substances as of decomposable, then there are two implications. The one is that those compoundings and recompoundings by which the elements were formed, must have been accompanied by degrees of heat exceeding any degrees of heat known to us. The other is that among these compoundings and recompoundings themselves, those by which the small-moleculed elements were formed produced more intense heat than those by which the large-moleculed elements were formed: the elements formed by the final recompoundings being necessarily later in origin, and at the same time less stable, than the earlier-formed ones.

      Note II. May we from these propositions, and especially from the last, draw any conclusions respecting the evolution of heat during nebular condensation? And do such conclusions affect in any way the conclusions now current?

      In the first place, it seems inferable from physico-chemical facts at large, that only through the instrumentality of those combinations which formed the elements, did the concentration of diffused nebulous matter into concrete masses become possible. If we remember that hydrogen and oxygen in their uncombined states oppose, the one an insuperable and the СКАЧАТЬ