Liquid Crystals. Iam-Choon Khoo
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Название: Liquid Crystals
Автор: Iam-Choon Khoo
Издательство: John Wiley & Sons Limited
Жанр: Техническая литература
isbn: 9781119705796
isbn:
(2.21)
Unlike the change in order parameter, which is a collective molecular effect, the change in density dρ arises from the individual responses of the molecules and responds relatively quickly to the temperature change.
These results are reflected in Figure 2.3a and b. The diffracted signal contains an initial “spike,” which rises and decays away in the time scale on the order of the laser pulse. As shown in more detail in Chapter 9, this contribution comes from laser‐induced electrostriction or density changes that affect local order. On the other hand, the slowly rising contribution comes from laser‐induced temperature rise ΔT and the resulting order parameter change S(ΔT). The rate of change depends on the temporal characteristics of the incident laser. The buildup time is about 175 μs with microsecond infrared (10.6 μm) laser pulse (cf. Figure 2.3a) and 30 μs with nanosecond visible (0.53 μm) laser pulse (cf. Figure 2.3b).
Dynamical grating diffraction is thus a useful optical tool to probe the dynamics of the response of order parameter for molecules in various electronic/rovibrational energy states; in particular, the critical “slowing down” of the order parameter near Tc as shown in Figure 2.4 for the observed order parameter response times as the temperature approaches Tc obtained with infrared microseconds laser pulses.
Figure 2.4. Observed buildup times of the diffracted signal associated with order parameter change as a function of the temperature vicinity of Tc; excitation by infrared microsecond laser pulses on E7 nematic film.
Figure 2.5. Schematic depiction of the molecular levels involved in ground electronic state rovibrational excitations by infrared photo absorptions and excited electronic state excitation by visible photo absorptions.
One can also see from the relative heights of the density and order parameter components in Figure 2.3a and b that the overall response of the nematic film is different for the two forms of excitation. Absorption of infrared photons (λ = 10.6 μm) corresponds to the excitation of the ground (electronic) state’s rovibrational manifold, whereas the visible photo‐absorption (λ = 0.53 μm) corresponds to excitation of the molecules to the electronically excited states (cf. Figure 2.5). The electronic molecular structures of these two excited states are different and may therefore account for the different dynamical response behavior of the order parameter, which is dependent on the intermolecular Coulombic dipole–dipole interaction.
More on order parameter dynamics in the context of nonlinear optical responses and switching devices based on laser‐induced order parameter changes in liquid crystals are given in Chapters 9 and 12.
2.4. ISOTROPIC PHASE OF LIQUID CRYSTALS
Above Tc, liquid crystals lose their directional order and behave in many respects like liquids. All bulk physical parameters also assume an isotropic form, although the molecules are anisotropic.
The isotropic phase is, nevertheless, a very interesting and important phase for both fundamental and applied studies. It is fundamentally interesting because of the existence of short‐range order, which gives rise to the critical temperature dependence of various physical parameters just above the phase transition temperature. These critical behaviors provide a good testing ground for liquid crystal physics.
On the other hand, recent studies have also shown that isotropic liquid crystals may be superior in many ways for constructing practical nonlinear optical devices (see Chapter 12), in comparison to the other liquid crystalline phases (see Chapter 8). In general, the scattering loss is less and thus allows longer interaction lengths, and relaxation times are on a much faster scale. These properties easily make up for the smaller optical nonlinearity for practical applications.
2.4.1. Free Energy and Phase Transition
We begin our discussion of the isotropic phase of liquid crystals with the free energy of the system, following deGennes’ pioneering theoretical development [1, 2]. The starting point is the order parameter, which we denote by Q.
In the absence of an external field, the isotropic phase is characterized by Q = 0; the minimum of the free energy also corresponds to Q = 0. This means that, in the Landau expansion of the free energy in terms of the order parameter Q, there is no linear term in Q; that is,
(2.22)
where F0 is a constant and A(T) and B(T) are temperature‐dependent expansion coefficients:
(2.23)
where T * is very close to, but lower than, Tc. Typically,
Note that F contains a nonzero СКАЧАТЬ