Organic Electronics for Electrochromic Materials and Devices. Hong Meng

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СКАЧАТЬ 4.2 × 10⁻⁴ −3.0 ∼ 3.0 22 No significant change [139] P(VDF‐TrFE)/PEO PEDOT:PSS 6.79 × 10⁻⁴ −1.0 ∼ 0.5 60 — [140] PEMA/poly (vinylidene fluoride) (PVdF)‐HFP WO₃//CeO₂–TiO₂ 1.46 × 10⁻⁶ −1.3 ∼ −0.8 81 — [141] PVdF‐HFP/silane‐functionalized ZrO₂ PANI:DBSA 1.78 × 10⁻³ −4.0 ∼ 4.0 70 — [142] PVDF‐HFP/POEI‐ISF₄ Nanofibers 8.62 × 10⁻³ 0 ∼ 1.2 68.7 95.5% of ΔT [143] PVDF‐co‐HFP/[EMI][TFSI] 1,1′‐bis(3‐fluoro‐4‐(trifluoromethyl)phenyl)‐4,4′‐bipyridinium bis(trifluoromethylsulfonyl)imide (TFMFPhV(TFSI)₂) 6.7 × 10⁻³ −0.35 ∼ 0 ∼73 ∼14% decrease of ΔT after 24 h [144] IL/PVDF‐HFP PEDOT:PSS 1.13 × 10⁻³ −1.4 ∼ 1.4 ∼24 — [54] TMPD/HV(BF₄)₂/SN/PVDF‐HFP TMPD/HV(BF₄)₂/succinonitrile 1 × 10⁻³ 0 ∼ 0.9 60.1 74.7% of the original ΔT after 2000 cycles [145] [Emim]BF₄/PMMA WO₃ 2.9 × 10⁻³(RT) −3.0 ∼ 1.5 88 — [146] Poly(ether ether ketone) membrane IR‐VEDs 6.8 × 10⁻³ −1.0 ∼ 1.0 47 Good cycling stability [147] PVDF‐HFP:PMMA/LiClO₄ — 2.83 × 10⁻⁴ — — — [148] PMMA/SN‐PC WO₃//brain natriuretic peptide (PBNPs) 1.46 × 10⁻³ −2.5 ∼ 2.0 52.4 44.5% after 2250 cycles [149] Poly(ε‐caprolactone) (PCL)/SiO₂ PEDOT: PSS 5.2 × 10⁻³ −4.0 ∼ 1.0 30.6 Good stability (100 cycles) [150] Polyvinyl butyral (PVB)‐based GPEFs WO₃//Ni_1−xO 4.0 × 10⁻⁵ −2.0 ∼ 2.0 65.8 Fading of 4.8% (16 h) [151] PAN–DMF–LiTFSI WO₃//CeO₂–TiO₂ 2.54 × 10⁻⁴ −2.0 ∼ 1.0 29.1 — [152] PADA LiNiO//WO₃ 1.33 × 10⁻² (RT) −2.30 ∼ 2.30 61 58.4% after 50 cycles [153] PVDF based P(PVK‐co‐EDOT) — −0.9 ∼ 0.5 39.1 — [154] 2‐APPG /PMDA/ICS WO₃ film 1.01 × 10⁻³ −3.5 ∼ 2.5 38.2 450 cycles [155]

Table 2.2 Examples of self‐healingand cross‐linking polymer electrolyte complexes and their respective highest ionic conductivities.

Electrolyte	Ionic conductivity (S/cm)	Electrochemical window (V)	Application	References
B‐PVA/KCl/graphene oxide (GO)	47.5 × 10−3	0 ∼ 1.0	Flexible energy‐storage device	[156]
SiO2–UPy	8.0 × 10−5	0 ∼ 6.0	Lithium‐ion batteries	[157]
P(AA‐VIm‐VSN)	1.26 × 10−4	−1.2 ∼ 0.3	Flexible electrochromic devices	[158]
[P(PO/EM)]/lithium trifluoro(perfluoro‐tert‐butyloxyl)borate (LiTFPFB)	1.55 СКАЧАТЬ В начало < 18 19 20 21 22 23 24 25 26 27 > В конец