The Principles of Biology, Volume 1 (of 2). Spencer Herbert

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СКАЧАТЬ so bound up as to be incapable of any relative movements (a supposition at variance with the conceptions of modern science) we must conceive them as severally able to vibrate in unison or harmony with those same classes of ethereal waves that affect them in their uncombined states. While the compound molecule as a whole will have some new rate of oscillation determined by its attributes as a whole; its components will retain their original rates of oscillation, subject only to modifications by mutual influence. Such being the circumstances of the case we may partially understand how the Sun's rays can effect chemical decompositions. If the members of a diatomic molecule stand so related to the undulations falling on them, that one is thrown into a state of increased oscillation and the other not; it is manifest that there must arise a tendency towards the dislocation of the two – a tendency which may or may not take effect, according to the weakness or strength of their union, and according to the presence or absence of collateral affinities. This inference is in harmony with several significant facts. Dr. Draper remarks that "among metallic substances (compounds) those first detected to be changed by light, such as silver, gold, mercury, lead, have all high atomic weights; and such as sodium and potassium, the atomic weights of which are low, appeared to be less changeable." As here interpreted, the fact specified amounts to this; that the compounds most readily decomposed by light, are those in which there is a marked contrast between the atomic weights of the constituents, and probably therefore a marked contrast between the rapidities of their vibrations. The circumstance, too, that different chemical compounds are decomposed or modified in different parts of the spectrum, implies that there is a relation between special orders of undulations and special orders of molecules – doubtless a correspondence between the rates of these undulations and the rates of oscillation which some of the components of such molecules will assume. Strong confirmation of this view may be drawn from the decomposing actions of those longer ethereal waves which we perceive as heat. On contemplating the whole series of diatomic compounds, we see that the elements which are most remote in their atomic weights, as hydrogen and the noble metals generally, will not combine at all, or do so with great difficulty: their vibrations are so unlike that they cannot keep together under any conditions of temperature. If, again, we look at a smaller group, as the metallic oxides, we see that whereas those metals which have atoms nearest in weight to the atoms of oxygen, cannot be separated from oxygen by heat, even when it is joined by a powerful collateral affinity; those metals which differ more widely from oxygen in their atomic weights, can be de-oxidized by carbon at high temperatures; and those which differ from it most widely combine with it very reluctantly, and yield it up if exposed to thermal undulations of moderate intensity. Here indeed, remembering the relations among the atomic weights in the two cases, may we not suspect a close analogy between the de-oxidation of a metallic oxide by carbon under the influence of the longer ethereal waves, and the de-carbonization of carbonic acid by hydrogen under the influence of the shorter ethereal waves?

      These conceptions help us to some dim notion of the mode in which changes are wrought in light in the leaves of plants. Among the several elements concerned, there are wide differences in molecular mobility, and probably in the rates of molecular vibration. Each is combined with one of the others, but is capable of forming various combinations with the rest. And they are severally in presence of a complex compound into which they all enter, and which is ready to assimilate with itself the new compound molecules they form. Certain of the ethereal waves falling on them when thus arranged, cause a detachment of some of the combined atoms and a union of the rest. And the conclusion suggested is that the induced vibrations among the various atoms as at first arranged, are so incongruous as to produce instability, and to give collateral affinities the power to work a rearrangement which, though less stable under other conditions, is more stable in the presence of these particular undulations. There seems, indeed, no choice but to conceive the matter thus. An atom united with one for which it has a strong affinity, has to be transferred to another for which it has a weaker affinity. This transfer implies motion. The motion is given by the waves of a medium that is relatively imponderable. No one wave of this imponderable medium can give the requisite motion to this atom of ponderable matter: especially as the atom is held by a positive force besides its inertia. The motion required can hence be given only by successive waves; and that these may not destroy each other's effects, it is needful that each shall strike the atom just when it has completed the recoil produced by the impact of previous ones. That is, the ethereal undulations must coincide in rate with the oscillations of the atom, determined by its inertia and the forces acting on it. It is also requisite that the rate of oscillation of the atom to be detached, shall differ from that of the atom with which it is united; since if the two oscillated in unison the ethereal waves would not tend to separate them. And, finally, the successive impacts of the ethereal waves must be accumulated until the resulting oscillations have become so wide in their sweep as greatly to weaken the cohesion of the united atoms, at the same time that they bring one of them within reach of other atoms with which it will combine. In this way only does it seem possible for such a force to produce such a transfer. Moreover, while we are thus enabled to conceive how light may work these molecular changes, we also gain an insight into the method by which the insensible motions propagated to us from the Sun, are treasured up in such ways as afterwards to generate sensible motions. By the accumulation of infinitesimal impacts, atoms of ponderable matter are made to oscillate. The quantity of motion which each of them eventually acquires, effects its transfer to a position of unstable equilibrium, from which it can afterwards be readily dislodged. And when so dislodged, along with other atoms similarly and simultaneously affected, there is suddenly given out all the motion which had been before impressed on it.

      Speculation aside, however, that which it concerns us to notice is the broad fact that light is an all-important agent of molecular changes in organic substances. It is not here necessary for us to ascertain how light produces these compositions and decompositions. It is necessary only for us to observe that it does produce them. That the characteristic matter called chlorophyll, which gives the green colour to leaves, makes its appearance whenever the blanched shoots of plants are exposed to the Sun; that the petals of flowers, uncoloured while in the bud, acquire their bright tints as they unfold; and that on the outer surfaces of animals, analogous changes are induced; are wide inductions which are enough for our present purpose.

      § 14. We come next to the agency of chief importance among those that work changes in organic matter; namely, chemical affinity. How readily vegetal and animal substances are modified by other substances put in contact with them, we see daily illustrated. Besides the many compounds which cause the death of an organism into which they are put, we have the much greater number of compounds which work those milder effects termed medicinal – effects implying, like the others, molecular re-arrangements. Indeed, most soluble chemical compounds, natural and artificial, produce, when taken into the body, alterations that are more or less manifest in their results.

      After what was shown in the last chapter, it will be manifest that this extreme modifiability of organic matter by chemical agencies, is the chief cause of that active molecular re-arrangement which organisms, and especially animal organisms, display. In the two fundamental functions of nutrition and respiration, we have the means by which the supply of materials for this active molecular re-arrangement is maintained.

      The process of animal nutrition consists partly in the absorption of those complex substances which are thus highly capable of being chemically altered, and partly in the absorption of simpler substances capable of chemically altering them. The tissues always contain small quantities of alkaline and earthy salts, which enter the system in one form and are excreted in another. Though we do not know specifically the parts which these salts play, yet from their universal presence, and from the transformations which they undergo in the body, it may be safely inferred that their chemical affinities are instrumental in working some of the metamorphoses ever going on.

      The inorganic substance, however, on which mainly depend these metamorphoses in organic matter, is not swallowed along with the solid and liquid food, but is absorbed from the surrounding medium – air or water, as the case may be. Whether the oxygen taken in, either, as by the lowest animals, through the general surface, or, as by the higher animals, through respiratory organs, is the immediate cause of those molecular changes which are ever going on throughout the living tissues; СКАЧАТЬ