Название: Magnetic Resonance Microscopy
Автор: Группа авторов
Издательство: John Wiley & Sons Limited
Жанр: Химия
isbn: 9783527827251
isbn:
Eiichi Fukushima
Albuquerque, 2021
Preface
Magnetic resonance microscopy (MRM) has focused on magnetic resonance imaging (MRI) applied to objects of smaller scale and higher spatial resolution for more than three decades. After the pioneering work by Eccles, Callaghan, Aguayo, Blackband, Johnson et al. in 1986, MRM quickly spread to, among other fields, chemistry, histology, and materials research. Since 1992, the edited book series Magnetic Resonance Microscopy has provided an important voice describing the latest developments in spatially resolved magnetic resonance methods and their applications far beyond the scope of medical diagnostics. An excellent introduction to MRM, focusing on the practical aspects of high magnetic fields and on the study of biological systems, was authored in 2017 by Luisa Ciobanu: Microscopic Magnetic Resonance Imaging: A Practical Perspective (Pan Stanford, Singapore, 2017). Our book complements this monograph by showing the use of MRM and related techniques in a much broader area and on a wider scale, which extends from chemical engineering to plant research and battery applications, highlighting the interdisciplinary nature of MRM.
The book opens with a section on hardware and methodology, covering aspects of micro-engineering, magnet technology, coil performance, and hyperpolarization to improve signal-to-noise ratio, a major bottleneck of MRM. Specific pulse sequences and developments in the field of mobile nuclear magnetic resonance are further topics of this first chapter. The following parts, 2 and 3, review essential processes such as filtration, multi-phase flows and transport, and a wide range of systems from biomarkers via single cells to plants and biofilms. Part 4 focuses on energy research, which is becoming increasingly important due to the globally growing environmental problems. It reports on battery types and their developments and how battery states can be recorded and characterized with MRM. However, we would like to point out to the reader that only a small sample of applications could be addressed in Chapters 1 to 4. Finally, the last chapter advocates that theory and applications should not be treated separately, because much can be gained from their complementarity.
The main aim of this book is to convince aspiring and established scientists from all fields that MRM is a versatile nuclear magnetic resonance (NMR) method that is capable of answering many questions from both the laboratory and everyday life. The book seeks to inspire a new readership from industries and innovative research directions to create synergies by adding MRM to their expertise.
The editors thank all the authors for contributing their invaluable knowledge to this book during a time challenged by COVID-19. Our thanks also go to the kind staff of the Wiley books department, who helped us with advice and support throughout the whole editing process.
Sabina Haber-Pohlmeier
Luisa Ciobanu
Bernhard Blümich
Summer 2021
1 Microengineering Improves MR Sensitivity
Neil MacKinnon, Jan G. Korvink, and Mazin Jouda
Institute of Microstructure Technology, Karlsruhe Institute of Technology, Eggenstein-Leopoldshafen, Germany
1.1 Introduction
Thirty years have passed since 1991 when Paul Callaghan published his book on magnetic resonance microscopy [1], and many works have subsequently appeared that have made numerous advances in this exciting field possible. Our goal for this chapter is to (informally) revisit some of Callaghan’s analysis, to reflect on it, and then take account of some of the advances and insights that have been reported since then.
1.1.1 Comparative Electromagnetic Radiation Imaging
Paul Callaghan’s book [1] is perhaps the first publication to consider magnetic resonance imaging (MRI) in the same light as optical microscopy. This will also be our starting point.
Until the advent of super-resolution microscopy, refractive optical microscopy was essentially a radiation scattering method, in which a beam of photons from an independent light source was sent on its way to scatter off objects, followed by traversal of the beam through a focusing objective on its way back to a detector, to thereby reveal the structure and composition of the scattering object. The limitations of this approach, in terms of resolution, is known as the Abbe limit δ = λ/(2 n sin θ), where n is the refractive index, θ the half-angle of the spot subtended by the lens, and λ the radiation wavelength.
Using radio waves taken for convenience at 300 MHz, a thus interpreted refractive MRI system would have a resolution of ~500 mm, which is a dire prospect for applications of MRI. In a seminal paper, Mansfield et al. [2] reported on a form of nuclear magnetic resonance (NMR) diffraction, in which they considered a solid-state periodic lattice of spins in a macroscopically sized lattice, revealing diffraction patterns on the order of the lattice. As a follow-up to this idea, Blümler et al. [3] and Bernhard Blümich [4] reported (the latter in a paper dedicated to Paul Callaghan) on an interesting intertwining of concepts of the k -space vector of refractive MRI and the spatial periodicity of a lattice-like diffractive structure, further exploring diffractive imaging. Blümich’s paper contains a few more gems СКАЧАТЬ