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Figure 1.7 (a) Schematic illustration of the design and fabrication of the asymmetric fiber‐based micro‐SC. (b) Comparative CV curves obtained for the GCF‐N2 and GCF/MnO₂‐10 fibers at the scan rate of 10 mV s⁻¹. (c) CV curves of one asymmetric micro‐SC, which are bended at different angles.

      Source: Reproduced with permission [109]. © 2014, Wiley‐VCH.

      1.3.2.2 Wrap‐Type Fiber AFSCs

The design of a wrap‐type AFSC is very similar to that of a parallel‐type fiber AFSC, which encapsulates two electrodes into a protective flexible tube instead of placing them on a flexible substrate [53, 59, 62,110–112]. Recently, Lu and his co‐workers [112] successfully synthesized N and low valence‐state Mo dual‐doped MoO₃ nanowires on carbon fibers, which was coupled with MnO₂@TiN‐loaded carbon fiber cathode and sealed with heat‐shrinkable tube to fabricate a wrap type solid‐state ASC (denoted as MnO₂@TiN//N‐MoO_3‐x) (Figure 1.8a). The galvanostatic charge/discharge (GCD) curves of MnO₂@TiN//N‐MoO_3‐x with different current densities in Figure 1.8b indicate that the stable operating voltage of the device reaches a significantly high value of 2.0 V. The ASC device also shows superior rate capability when current density increased by 15 folds (Figure 1.8c). More importantly, the excellent flexibility and mechanic robustness enabled the fiber AFSC device to perfectly maintain its electrochemical performances in bent and even knotted conditions (Figure 1.8d). Benefiting from the ultrahigh output voltage and Faradaic electrodes with improved conductivity, the MnO₂@TiN//N‐MoO_3‐x device exhibited a maximum energy and power density of 2.29 mW h cm⁻³ and 1.64 W cm⁻³ respectively, outperforming many other fiber‐shaped SC devices reported (Figure 1.8e).

Figure 1.8 (a) Schematic illustration of the as‐assembled fiber‐shaped MnO₂@TiN//N‐MoO_3‐x‐ASC device. (b) GCD curves of our fiber‐shaped AFSC device. (c) Linear capacitances and volumetric capacitances of the fiber‐shaped AFSC device as a function of current density. (d) CV curves collected at 100 mV s⁻¹ for the fiber‐shaped AFSC device under different conditions (left) and corresponding device pictures (right). (e) Ragone plots for the fiber‐shaped AFSC device and other recently reported fiber‐shaped FSCs.

      Source: Reproduced with permission [112]. © 2016, Wiley‐VCH.

      1.3.2.3 Coaxial‐Helix‐Type Fiber AFSCs

By helically wrapping a wire shape axial electrode with another wire electrode, coaxial‐helix‐type ASCs with core–shell cable‐like structures have been creatively explored [86, 113–117]. For example, the Thomas group [117] fabricated a novel cable‐like coaxial‐helix‐type AFSC as illustrated in Figure 1.9a. The AFSC device was coaxially assembled using wire‐shaped electrodes, where the MnO₂@AuPd@CuO nanowiskers@copper wire core‐shell‐structured cathode was fabricated via a three‐step synthesis, and the Fe₂O₃@carbon fiber core‐shell‐structured anode was prepared through hydrothermal growing followed by conversion. The AFSC device could tolerate different bending states from 0^° to nearly 180° (Figure 1.9b), while its promising electrochemical performances such as quasi‐rectangular‐shaped CV curves, maximum output voltage of 1.8 V and volumetric capacitance of 1.6 F cm⁻³ did not sacrifice (Figure 1.9c). Furthermore, the AFSC device could serve as a bi‐functional integrated electrical cable for both electricity storage and electricity transmission.

Figure 1.9 (a) Schematics illustration shows the fabrication process of an anode and a cathode, respectively, and the structure of a coil‐type asymmetric supercapacitor electrical cable. (b) Optical images of a coil‐type asymmetric supercapacitor electrical cable at different bending states. (c) CV curves obtained at different bending states at 200 mV s⁻¹.

      Source: Reproduced with permission [117]. © 2015, Wiley‐VCH.

      1.3.2.4 Two‐Ply‐Yarn‐Type AFSCs

Fiber AFSCs with stand‐alone two‐ply‐yarn type configuration has been proposed for efficient weaving into textiles, which are constructed by coating two fiber electrodes with polymer electrolyte and then twisting them together without outer packaging [118–120]. As shown in Figure 1.10a, Jin et al. [118] recently employed carbon‐fiber‐thread@polyaniline as cathode and functionalized carbon‐fiber thread as anode to fabricate a two‐ply‐yarn‐type AFSC device with PVA‐H₃PO₄ gel electrolyte. The device successfully reached a high operating voltage of 1.6 V with energy density up to 2 mW h cm⁻³. In order to demonstrate its potential in practical applications, the device was woven into a glove (Figure 1.10b) and exhibited excellent mechanical tolerance against bending (Figure 1.10c). The flexibility of the device was also examined via stretching to even 100% (Figure 1.10d), while the capacitance of the stretched device merely changed (Figure 1.10e).

1.4 Summary

      To conclude, AFSCs have been universally accepted as one of the most promising energy storage devices, which effectively utilize the different potential windows of the pseudocapacitive cathodes and electric double‐layer СКАЧАТЬ