Encyclopedia of Renewable Energy. James G. Speight
Чтение книги онлайн.

Читать онлайн книгу Encyclopedia of Renewable Energy - James G. Speight страница 97

Название: Encyclopedia of Renewable Energy

Автор: James G. Speight

Издательство: John Wiley & Sons Limited

Жанр: Физика

Серия:

isbn: 9781119364092

isbn:

СКАЧАТЬ

      A benchmark crude oil is a crude oil that is used as the standard crude oil against which the properties of the (liquid) source of any fuel (even a renewable fuel) can be measured or compared. When evaluating the price of any crude oil, it is important to compare the crude oil against an appropriate benchmark crude oil.

      The price of crude oil means the spot price of either West Texas Intermediate crude oil as traded on the New York Mercantile Exchange (NYMEX) for delivery in Cushing, Oklahoma, or of Brent crude as traded on the Intercontinental Exchange (ICE, into which the International Petroleum Exchange has been incorporated) for delivery at Sullom Voe. The price of a barrel of oil is highly dependent on both its grade, determined by factors such as its specific gravity or API gravity and sulfur content, as well as location. The vast majority of oil is not traded on an exchange but on an over-the-counter basis, typically with reference to a marker crude oil grade that is typically quoted via pricing. Other important benchmark crude oils include Dubai, Tapis, and the OPEC basket.

      A light crude oil is generally one with an API gravity of less than approximately 40 – for example, Brent crude oil has an API gravity on the order of 38 to 39°. Sweet crude is preferable to sour crude oil because it is also (like light crude) more suited to the production of the most valuable refined products. On the other hand, heavy crude oil has high density, high viscosity, and high sulfur content making it more difficult to transport and refine and cheaper to purchase. Typically, sour crude oil has a sulfur content above 0.5% by weight and is usually heavy crude oil, making it cheaper to purchase but more expensive to refine.

      Heavy crude oil will typically have an API gravity of 20 or less - the higher the API gravity, the lower the density. Heavy crude oil is harder to handle (it is too thick to pump easily through pipelines unless diluted with light crude) and is more expensive to refine to produce the most valuable crude oil products such as naphtha (gasoline), kerosene, diesel fuel, and aviation fuel.

      Because there are so many different varieties and grades of crude oil, buyers and sellers have found it easier to refer to a limited number of reference, or benchmark, crude oils. Other varieties are then priced at a discount or premium, according to their quality. Thus, crude oil is priced in terms of regional blends, each with different characteristics. Of these, certain blends are followed by traders, as they most reflect the overall value of oil, and therefore affect the way different blends are priced. These are essentially like a Consumer Price Index for different types of oil. Approximately 160 different types of crude are traded around the world; the four primary benchmarks, of which these are priced internationally are (i) Brent blend crude oil, (ii) West Texas intermediate (WTI) crude oil, (iii) Dubai crude oil, and (iv) the OPEC Basket crude oil.

      The Brent crude oil blend is based on the prices of Brent crude, which is a light, sweet crude oil and is actually a combination of crude oil from 15 different oil fields in the Brent and Ninian systems located in the North Sea. The API gravity is 38.3° (making it a “light” crude oil, but not quite as “light” as West Texas Intermediate crude oil), while it contains approximately 0.37% by weight sulfur (making it a sweet crude oil, but again slightly less sweet than West Texas Intermediate crude oil). The Brent blend is ideal for making gasoline and middle distillates, both of which are consumed in large quantities in Northwest Europe, where Brent blend crude oil is typically refined. However, if the arbitrage between Brent and other crude oils, including WTI, is favorable for export, Brent has been known to be refined in the United States (typically the East Coast or the Gulf Coast) or the Mediterranean region. Brent blend, like West Texas Intermediate crude oil, production is also on the decline, but it remains the major benchmark for other crude oils in Europe or Africa.

      Beta Decay

      Beta decay (β-decay) is a type of radioactive in which a beta particle (a fast energetic electron or positron) is emitted from an atomic nucleus which transforms the original nuclide to an isobar of that nuclide.

      By definition, an isobar is an atom (nuclide) of different chemical elements that have the same number of nucleons. Correspondingly, an isobar differs in atomic number (or the number of protons) but has the same mass number. An example of a series of isobars is 40S, 40Cl, 40Ar, 40K, and 40Ca.

      Thus, the beta decay of a neutron transforms it into a proton by the emission of an electron accompanied by an antineutrino or, conversely, a proton is converted into a neutron by the emission of a positron with a neutrino in the positron emission reaction. Neither the beta particle nor its associated (anti-)neutrino exist within the nucleus prior to beta decay, but are created in the decay process. By this process, unstable atoms obtain a more stable ratio of protons to neutrons. The probability of a nuclide decaying due to beta and other forms of decay is determined by the nuclear binding energy.

      An example of electron emission (β decay) is the decay of carbon-14 (14C) into nitrogen-14 (14N) with a half-life on the order of 5,730 years:

images

      In this form of decay, the original element becomes a new chemical element (nuclear transmutation) and the new element has an unchanged mass number (A) but anatomic number (Z) that is increased by one. As in all nuclear decays, the decaying element (in this case 146C) is the parent nuclide, while the resulting element (in this case 147N) is known as the daughter nuclide.

      Another example is the decay of hydrogen-3 (3H, tritium) into helium-3 (3He) with a half-life on the order of 12.3 years:

images

      An example of positron emission (β+ decay) is the decay of magnesium-23 (23Mg) into sodium-23 (23Na) with a half-life on the order of 11.3 seconds:

images

      Beta+ decay (β+ decay) also results in nuclear transmutation, with the resulting element having an atomic number that is decreased by one.

      See also: Alpha Decay, Alpha Particle, Nuclear Energy.

      Beta Particle

      A beta particle is emitted from the nucleus of a radioactive atom with a wide range of energies up to some maximum value. When a beta particle is emitted that is below the maximum value, the neutrino carries away the rest of the energy.

      Like the alpha particles, beta particles, like alpha СКАЧАТЬ