Non-halogenated Flame Retardant Handbook. Группа авторов

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СКАЧАТЬ has led to consumer advocates/consumer influences asking for non-halogenated FRs in certain applications. To date, no one is clamoring for halogenated flame retardants, but there are many customer requests for non-halogenated FR use in consumer electronics and items that need fire protection, and have a short useful lifetime. The coming regulations seeming to ban all flame retardant chemicals by broad class may eventually lead to customer requests for no-flame retardant chemicals to be added to a product, and to instead use inherently low flammable materials. This latter request only holds if the cost is right, and for now, cost is still “king” in regards to what most consumers will pay. A consumer may specifically request non-halogenated chemistry and/or lower environmental impact items, but rarely will pay more for it.

Political considerations based upon perception of scientific information, rather than actual interpretation of data and studying the entire complex picture of fire safety and materials science, are indeed something that must be considered as a non-fire issue affecting flame retardant use. Perversely, these political motivations are moving to change the fire safety regulations to weaken them such that no flame retardant chemicals are needed. It is fair to state that sometimes regulations outlive their historical use as technology and consumer use trends change over time. But the materials do not change or lose their flammability with time. The main example of this political move is associated with polyurethane foam used in furniture. Polyurethane foam, due to its chemical structure, is a highly flammable material [71–75], and is just as flammable today as it was in the 1970s when fire safety regulations were first put in place around furniture. In the US, California Technical Bulletin #117 (TB-117) and Technical Bulletin #133 (TB-133) were put in place with small and large flame exposure tests to ensure the foams could not propagate a fire beyond that initial ignition source. As such, flame retardant chemicals were added to the polyurethane foam to allow them to pass this test and be sold into commerce. Some of those flame retardants were found to have negative PBT profiles, but instead of banning the critical flame retardants in question (which unfortunately takes a long time and is complicated), the fire safety standard was changed and morphed into a smolder-only test in 2013 [76]. This new test method may end up protecting against cigarette ignition sources causing furniture to ignite (although there is still a lot of debate about the effectiveness of this test) [77], but it provides no fire protection against open flame sources. While no flame retardants are required to pass the new TB-117 2013 test, the heat release of the polyurethane foam is still very high, and if it ignites, will still lead to major fire losses [24, 78]. To date, this is the only case of fire safety regulations becoming weakened to provide an incentive to not use flame retardant chemicals, but it is a dangerous precedent. Hopefully fire losses do not have to increase in California (and other places) before arguments are made to require higher levels of fire safety while also demanding no hazardous chemicals can be used.

1.5 Regulatory Outlook and Future Market Drivers

      Based upon current information as of the writing of this chapter, the regulatory outlook appears to have more regulations of flame retardants, not less, in the coming decade. There will be regional pushes for regulations of chemicals, with the EU continuing to push the most regulation via existing protocols (RoHS, WEEE) and newer broader chemical registration programs (REACH). The US will remain fragmented at the state level since federal regulations will continue to be delayed until such time as the US legislative branch writes and passes new regulations. Some US states will continue to promote bans on flame retardant chemicals by class, rather than by specific structure. Other countries are expected to maintain their regulations, and perhaps selectively strengthen them where there is national will to do so. Because of the emphasis on PBT for chemical use, polymeric and reactive flame retardant use is expected to grow, while small-molecule additives/non-reactive flame retardant use is expected to shrink in the coming decade. Issues with plastic waste and end-of-lifetime/sustainability issues may further push some flame retardants out of use if they can migrate out of the plastic, or, prevent recycling or clean disposal of said plastic waste. Vigilance by fire safety scientists and fire safety engineers is required to push back against regulations which weaken fire safety under the guise of improving environmental and personal health and safety, as the pollution damage from accidental fires far outweighs the pollution from using flame retardant chemicals. That being said, we can have improved fire safety and eliminate chemicals of concern – it does not need to be one or the other. The correct choice of material and fire protection solution can deliver both, and fire safety regulations do not need to be weakened, nor do all chemicals with potential flame retardant benefit need to be regulated out of existence.

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