Patty's Industrial Hygiene, Physical and Biological Agents. Группа авторов
Чтение книги онлайн.

Читать онлайн книгу Patty's Industrial Hygiene, Physical and Biological Agents - Группа авторов страница 20

Название: Patty's Industrial Hygiene, Physical and Biological Agents

Автор: Группа авторов

Издательство: John Wiley & Sons Limited

Жанр: Химия

Серия:

isbn: 9781119816225

isbn:

СКАЧАТЬ out of the atom, and the atom is said to be ionized. Ionization is the process of separating an electron from an atom, thereby upsetting the electrical neutrality of the atom and producing a pair of electrically charged particles – the ejected electron, which is the negative ion, and the residual atom, which is a positive ion. Work must be done by the ionizing particle, the alpha or beta particle, to separate the electron from its atom. An alpha particle loses an average of about 35.5 eV of energy per ion pair produced in air or in soft tissue, while a beta particle loses an average of about 34 eV per ionizing collision. These “collisions” are in reality interactions between the electric fields associated with the ionizing particles and the electrons in the absorbing media. Because an alpha particle has a large mass, moves slowly, and is doubly charged, it has a high rate of ionizing collisions, and consequently a high rate of energy loss. This high rate of energy loss explains the very low penetration of alpha radiation into matter. The linear rate of ion production is called the specific ionization. In air, the specific ionization of alpha particles is of the order of 104–105 ion pairs per centimeter 5.

      Beta particles have only a single charge and travel at speeds near that of light. As a consequence, the specific ionization of beta particles is relatively low. While an alpha particle produces of the order of 50 000 ion pairs per centimeter in air, a beta particle in air produces only about 100 ion pairs per centimeter. This difference in the specific ionization between the two types of radiation is important in health physics for several reasons. First, it accounts for the higher penetrating power of beta particles than that of alpha radiation. For example, a 1.71‐MeV beta penetrates tissue to a depth of about 8 mm, while a 5.3‐MeV alpha, which has three times the energy, penetrates only about 0.005 cm of tissue. Second, it is utilized in the design of radiation‐measuring instruments sensitive to this difference in order to be able to distinguish between the two types of radiation.

      4.3 Bremsstrahlung

      Bremsstrahlung (from the German meaning “braking radiation”) is the production of X‐rays when a charged particle undergoes a sudden change in velocity. When a high‐speed electron collides with an atomic nucleus electric field, there is an abrupt change in the particle's velocity, and a fraction of the particle's kinetic energy is converted into X‐rays. This fraction is extremely small for low‐energy betas and for low atomic numbered absorbers, but it increases with increasing energy and with increasing atomic number. For this reason, beta shields are made of materials of low atomic number. In practice, beta‐shielding material of atomic number higher than 13 (Al) is seldom used.

      Second, bremsstrahlung X‐rays are an unwanted side effect of shielding betas or in an instrument or other device in which electrons are accelerated across high voltages, such as an electron microscope, a klystron microwave generator, or an electron beam metallurgical furnace. Since these devices are not intended to be used as an X‐ray source, these unwanted X‐rays can pose a serious hazard if the user or the industrial hygienist is unaware of their existence.

      4.4 Electromagnetic Radiation

      In a vacuum, the wave length, λ, and the frequency, f, of these waves are related to their speed, c, by

      (6)

      Wavelength is frequently expressed in angstrom units (1 Å unit = 10−10 m). According to the wave model, the energy carried by the waves is proportional to the square of the amplitude of the electric and magnetic field strengths.

      The wave model of electromagnetic radiation is useful for explaining many, but not all physical phenomena, and is the basis for understanding the effects of nonionizing electromagnetic energy. Phenomena that are not amenable to explanation by the wave theory are explainable by the quantum theory. According to the quantum theory, electromagnetic radiation behaves as if it consists of particles of energy, called photons, which travel through space at the speed of light (3 × 108 m s−1). Each particle contains a discrete quantity, or “quantum” of electromagnetic energy. Ionizing radiation includes photons whose energy exceeds 12 eV. The photon's energy content is proportional to the frequency of the radiation when the radiation is considered as a wave, and is given by

      (7)

      where h is Planck's constant and has a value of 6.626 × 10−34 J s, and the frequency, f, is in hertz.

      4.4.1 Interaction with Matter

      Ionizing photons (X‐rays and gamma rays) interact with absorbing media by several different competing mechanisms, depending on the quantum energy and the atomic number of the absorber. Two of these mechanisms, photoelectric absorption СКАЧАТЬ